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If I subject it to a drastic change in temperature then it would break, but that's not what I tried. I let it come down to ambient temp after the boiling. Then I put the stem in hot water and put a little crushed ice in the bowl. The joint wasn't directly exposed to either the hot or the cold...

I've got a long glass stem with a sliding bowl, and the bowl and stem are impossibly cemented together. I tried soaking them in alcohol over night, and that didn't help. Then I tried boiling it to soften the resin, but that didn't help either. They are cooling right now and in a couple minutes...